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triflic anhydride

CAS No.: 358-23-6      Formula: C2F6O5S2

Weight: 282.13900

Synonyms: TRIFLUOROMETHANESULFONIC ANHYDRIDE (10 ML ); TRIFLUOROMETHANESULFONIC ANHYDRIDE FOR SYNTHESIS; TRIFLUORO METHANESULFONIC ANHYDRIDE; Trifluoromethanesulfonicanhydride; TRIFLIC ANHYDRIDE; (TRIFLUOROMETHANE)SULFONYL TRIFLUOROMETHANESULFONATE; TRIFLUOROMETHANESULFONIC ACID ANHYDRIDE; TRIFLUOROMETHANESULFONIC ACID; TRIFLUOROMETHANESULPHONIC ANHYDRIDE; TRIFLUOROMETHANE SULFONIC ANHYDRIDE; TRIFLUOROMETHANESULPHONIC ACID ANHYDRIDE; TRIFLUOROMETHANE-SULFONICANHYDRIDE; TRIFLUOROMETHANESULFONIC ANHYDRIDE (TRIFLIC ANHYDRIDE); TRIFLUOROMETHANESULPHONICACIDANHYDRIDE; Trifluoromethanesulfonic anhydride;


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Description

Triflic anhydride is the chemical compound with the formula (CF3SO2)2O. This compound is a particularly strong electrophile, useful for introducing the triflyl group, CF3SO2. Triflic anhydride is the acid anhydride of the strong acid triflic acid, CF3SO2OH. It can be assayed by 19F NMR spectroscopy: −72.6 ppm vs. -77.3 for TfOH (std CFCl3).

Basic Information
CAS No.:
358-23-6
Synonyms:
TRIFLUOROMETHANESULFONIC ANHYDRIDE (10 ML ); TRIFLUOROMETHANESULFONIC ANHYDRIDE FOR SYNTHESIS; TRIFLUORO METHANESULFONIC ANHYDRIDE; Trifluoromethanesulfonicanhydride; TRIFLIC ANHYDRIDE; (TRIFLUOROMETHANE)SULFONYL TRIFLUOROMETHANESULFONATE; TRIFLUOROMETHANESULFONIC ACID ANHYDRIDE; TRIFLUOROMETHANESULFONIC ACID; TRIFLUOROMETHANESULPHONIC ANHYDRIDE; TRIFLUOROMETHANE SULFONIC ANHYDRIDE; TRIFLUOROMETHANESULPHONIC ACID ANHYDRIDE; TRIFLUOROMETHANE-SULFONICANHYDRIDE; TRIFLUOROMETHANESULFONIC ANHYDRIDE (TRIFLIC ANHYDRIDE); TRIFLUOROMETHANESULPHONICACIDANHYDRIDE; Trifluoromethanesulfonic anhydride;
Formula:
C2F6O5S2
Molecular Weight:
282.13900
PSA:
94.27000
LogP:
2.86380
Properties
Appearance & Character:
Contact with air smoke, hygroscopic, with pungent odor of the liquid.
Density:
1.677 g/mL at 25 °C(lit.)
Melting Point:
-80°C
Boiling Point:
81-83 °C(lit.)
Flash Point:
81-83°C
Storage Conditions:
Refrigerator
Safety Info
Symbol:
GHS05、GHS08
Signal Word:
Dangerous
Hazard Statement:
H302; H314
Warning Statement:
P280; P305 + P351 + P338; P310
Customs Code:
29049020
WGK Germany:
3
Hazard Category Code:
R14; R21/22; R34; R35
Security Instructions:
S26; S36/37/39; S43
Dangerous Goods Sign:
C